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Rise from erebus mechanos strategy11/24/2023 ![]() 2014).Įrebus volcano on Ross Island, Antarctica, is an excellent natural laboratory to study magma degassing from a long-lived lava lake. With an increasing body of experimental work to understand the solubility and redox relationships of different volatile species, thermodynamic models for degassing that incorporate empirical solubility laws are becoming available (Burgisser et al. However, interpreting degassing history is complicated since the composition of the gas phase changes as magma ascends. Gerlach and Nordlie 1975 Giggenbach 1987). If the measured gas species are in thermodynamic equilibrium, the pressure and temperature conditions for a given composition can be calculated from known equilibrium constants, provided that sufficient numbers of redox equilibria are constrained (e.g. Inverse modelling of plume gas measurements to characterise their origins therefore provides insights into the deeper processes driving surface behaviour. The interaction between gas and melt is a key control on the nature of volcanic activity. The composition of gases emitted by volcanoes is the result of a complex set of conditions, including initial magma composition, pressure, temperature, ascent pathways, and the degree of physical and chemical coupling between gas and melt. We interpret the cycles to arise from recharge of the lake by intermittent pulses of magma from shallow depths, which degas H 2O at low pressure, combined with a background gas flux that is decoupled from this very shallow magma degassing. The ‘peaks’ of the cycles, defined by maxima in H 2O and SO 2 column amounts, coincide with high CO 2/CO ratios and proportionally smaller increases in column amounts of CO 2, CO, and OCS. Notably, the wavelet analysis shows a persistent periodicity in the CO 2/CO ratio and strong periodicity in H 2O and SO 2 degassing. This reveals (i) a cyclic change in total gas column amount, a likely proxy for gas flux, with a period of about 10 min, and (ii) a similarly phased cyclic change in proportions of volcanic gases, which can be explained in terms of chemical equilibria and pressure-dependent solubilities. In order to understand more fully the nature and origins of these cycles, we present here a wavelet-based frequency analysis of time series measurements of gas emissions from the lava lake, obtained by open-path Fourier transform infrared spectroscopy. ![]() ![]() Field observations have previously identified rapid cyclic changes in the behaviour of the lava lake of Erebus volcano. ![]()
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